26. Prevention of
Organic Solvent Poisoning |
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Organic solvents are used in manufacturing processes of various products
in factories and many other industrial sites. In these processes, a significant
number of health problems including acute poisoning have occurred. To prevent
such problems, employers are obligated to do the following:
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1. Regulated substances
(Organic solvents or organic solvent mixtures containing organic solvents
at more than 5 wt.% : hereafter referred to as Organic solvent substances,
etc."): 54 substances
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a. |
Class-1 organic solvents: 7 substances, i.e., chloroform, carbon tetrachloride,
1,2-dichloroethane, 1,2-dichloroethylene, 1,1,2,2-tetrachloroethane, trichloroethylene
and carbon disulfide
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b. |
Class-2 organic solvents: 40 substances including acetone, ethylether,
xylene, butyl acetate, styrene, trichloroethylene and n-hexane
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c. |
Class-3 organic solvents: 7 substances, i.e., gasoline, coal-tar naphtha,
petroleum ether, petroleum naphtha, petroleum benzine, turpentine oil and
mineral spirit
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2.Organic solvents work
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a. |
Manufacturing processes of organic solvents, etc.; work to filter, mix,
stir or heat organic solvents, etc. in the manufacturing processes of dyes,
pharmaceuticals, agricultural chemicals, synthetic resin or their intermediates
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b. |
Printing operations carried out by using a material containing an organic
solvent
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c. |
Work involving drawing letters or pictures using a material containing
an organic solvent
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d. |
Varnishing, waterproofing and other surface treating work carried out by
using organic solvents, etc.
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e. |
Work involving applying organic solvents, etc. for bonding, and work involving
bonding objects to which organic solvents, etc. have been applied
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f. |
Cleaning or wiping operation carried out by using organic solvents, etc.
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g. |
. Painting operation carried out by using organic solvents, etc.
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h. |
Work involving drying objects to which organic solvents, etc. are adhered
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j. |
Testing or research work carried out by using organic solvents, etc.
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j. |
Work carried out in tanks that have contained organic solvents, etc.
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3. Fundamental preventive measures
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a. |
Equipment
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Class-1 and class-2 organic solvents, etc.: Equipment to seal up the emitting
source of organic solvent vapour, local exhaust ventilation system or push-pull
type ventilator
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Class-3 organic solvents, etc.: Equipment to seal up the emitting source
of organic solvent vapour, local exhaust ventilation system, push-pull
type ventilator or general ventilator. Nevertheless, for work carried out
in a tank, a general ventilator must not be used.
For an indoor workplace of which the walls have two or more open sides
or when workers put on air-supplied respirator for short-time work, the
installation of equipment may be omitted.
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b. |
Health examination
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Work to handle class-1 and class-2 organic solvents, etc. in indoor workplaces
and work to handle class-3 organic solvents, etc. in tanks (Health examination
required at least once every 6 months).
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c. |
Performance standards of local exhaust ventilation system, etc.
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For local exhaust ventilation system, etc., the type of hood, air cleaner,
the position of exhaust opening, the controlled air velocity, the ventilation
volume and the like are stipulated.
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4. Management
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a. |
Appointment of operations chief
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For work involving manufacturing or handling a substance listed in (1),
an operations chief who has completed a definite skilll training course
must be appointed.
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b. |
Periodical voluntary inspection
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Periodical voluntary inspection of local exhaust ventilation sysytem, etc.
should be carried out at least once a year, and the results and records
of repair must be kept for three years.
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c. |
Notice
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A notice indicating the following matters should be posted in a prominent
place for workers handling organic solvents:
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(a) |
Effect of organic solvents on the human body
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(b) |
Precautions in handling organic solvents, etc..
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(c) |
First aid treatment in the case of organic solvent poisoning
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d. |
Indications of organic solvent classes
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Class-1 organic solvents, etc.: Red
Class-2 organic solvents, etc.: Yellow
Class-3 organic solvents, etc.: Blue
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e. |
Working environment measurement
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In indoor workplaces where class-1 and class-2 organic solvents are handled,
the working environment should be measured at least every 6 months and
equipment or working processes should be improved.
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5. Exemption from application of the provisions
In case only a small amount of an organic solvent is consumed, such obligations as the installation of equipment, assignment of an operations chief, posting of a notice, indications and so forth are exempted.
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The next article in the series will be on the prevention of health damage likely to be caused by specified chemical substances, etc.
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